运用3DEEMs及荧光偏振方法研究pH、离子强度及浓度效应对腐殖酸荧光光谱特性的影响   总被引：6，自引：0，他引：6  

梅毅  吴丰昌  王立英  白英臣 《地球化学》2008,37(2):165-173

利用三维荧光激发.发射光谱(3DEEMs)及荧光偏振法研究了3例腐殖酸和1例湖泊溶解有机物(DOM)在不同腐殖酸浓度、离子强度和pH条件下的荧光光谱特性.实验结果表明,随着浓度增大,各腐殖酸样的荧光强度增大,其中垃圾渗滤液腐殖酸和Pahokee泥炭腐殖酸的荧光峰出现红移.随着浓度进一步增大,腐殖酸的荧光偏振值增大,由此推断在此浓度范围内腐殖酸由于分子间的排斥作用使其构型出现伸展.离子强度增大导致腐殖酸及阿哈湖DOM的荧光强度降低.随着氯化钾(KCI)浓度增大,Fluka腐殖酸的荧光峰A蓝移,荧光峰B的荧光偏振值出现减小,推测是由于静电中和作用使其荧光基团发生卷曲造成的.离子强度对其余腐殖酸样和阿哈湖DOM的其他荧光特性没有明显的影响.总的来说,pH值的变化对腐殖酸和湖泊DOM的荧光特征的影响是很明显的.随着pH值增大,腐殖酸和湖泊DOM的荧光强度增强.而pH值减小时,Fluka腐殖酸和Pahokee泥炭腐殖酸的荧光峰(A峰)蓝移,当pH值降到5时,Fhka腐殖酸的荧光峰突然红移到最大,随后又继续蓝移;垃圾渗滤液腐殖酸和阿哈湖DOM的荧光峰位无明显的漂移.所有样品的荧光偏振值都减小(但阿哈湖DOM的A峰变化不大),但在pHi≤5时又增大,这种现象表明随着pH值降低,腐殖酸和湖泊DOM中有机大分子发生卷曲,但在pH≤5时由于羧基的质子化又以平面伸展构型出现在溶液中.  相似文献   

喜马拉雅山脉的地质地貌特征:来自SRTM数字高程模型和降水量数据的约束   总被引：3，自引：1，他引：2       下载免费PDF全文

王猛  刘焰  何延波  魏东 《地质科学》2008,43(3):603-622

利用GTOPO30和SRTM3数字高程(DEM)数据,提取了喜马拉雅山脉(造山带)的数字高程模型并对其进行了地质地貌的初步分析。从SRTM3数字高程数据提取出坡度数据,初步分析了喜马拉雅山脉坡度和高程的特征。数字高程和坡度图清楚地展现了喜马拉雅大型断裂带(构造边界)的空间分布特征。分析了中国气象局下属的西藏、青海、四川和云南4省区气象观测台站55年来的年平均降水量观测数据、喜马拉雅山脉南坡的年平均降水量数据、喜马拉雅DEM和裂变径迹数据,发现喜马拉雅山脉从东至西,年平均降水量逐渐减少,地形起伏逐渐变小,而高程渐次升高,与此同时剥蚀速率降低;从北至南,年平均降水量逐渐增加,地形起伏增大,高程快速降低,而剥蚀速率则急剧升高。这充分说明了喜马拉雅年平均降水量大的地区,地表剥蚀作用相对较强,年平均降水量小的地区,地表剥蚀作用则较弱,即:在喜马拉雅地区,长周期的地表剥蚀过程(可长达数个百万年时间尺度)和短周期(仅仅50年)的降水量观测是耦合的。  相似文献   

松辽盆地三肇凹陷葡萄花油层成藏模式初探   总被引：11，自引：5，他引：6       下载免费PDF全文

孙雨  马世忠  刘云燕  刘宗堡  于利民 《地质科学》2008,43(4):746-757

运用源控含油气系统理论与综合分析技术,按成藏“层次分析”方法,通过对生、储、盖、圈(闭)静态要素及其内生、排、运、聚、散(失)动态过程的综合研究,对松辽盆地中央坳陷的三肇凹陷葡萄花油层成藏条件进行探讨,提出了以次级凹陷为中心、不同类型的油气聚集带紧邻并围绕次级凹陷最低部位呈环带状分布的大型凹陷内成藏模式,并进一步提出永乐次级凹陷中心及其三级聚油环带及徐家围子次级凹陷以西为"网式"运聚特征;在凹陷级成藏模式的指导下,通过对大面积密井网开发区综合解剖,提出三级构造带中单个的局部构造圈闭(群)、单个的(局部构造——)岩性圈闭(群)控油和成藏规律,为认识本区基本控油单元、油水分布规律、油气勘探及扩大新探区提供重要的理论依据。  相似文献   

Interference of Multiple Strip Footings on Sand Using Small Scale Model Tests   总被引：2，自引：1，他引：1  

Jyant Kumar  Manas Kumar Bhoi 《Geotechnical and Geological Engineering》2008,26(4):469-477

By using small scale model tests, the interference effect on the vertical load-deformation behavior of a number of equally spaced strip footings, placed on the surface of dry sand, was investigated. At any stage, all the footings were assumed to (i) carry exactly equal magnitude of load, and (ii) settle to the same extent. No tilt of the footing was permitted. The effect of clear spacing (s) among footings on the results was explored. A new experimental setup was proposed in which only one footing needs to be employed rather than a number of footings. The bearing capacity increases continuously with decrease in spacing among the footings. The interference effect becomes further prominent with increase in soil friction angle. In contrast to an increase in the bearing capacity, with decrease in spacing of footings, an increase in the footing settlement associated with the ultimate state of shear failure was observed. The present experimental observations were similar to those predicted by the available theory, based on the method of characteristics. As compared to the theory, the present experimental data, however, indicates much greater effect of interference especially for larger spacing among footings.  相似文献   

铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成   总被引：22，自引：5，他引：17  

朱祥坤  李志红  赵新苗  唐索寒  何学贤  Nick S. Belshaw 《岩石矿物学杂志》2008,27(4):263-272

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).  相似文献   

强降雨条件下土质边坡瞬态稳定性分析   总被引：9，自引：1，他引：8  

吴长富  朱向荣  尹小涛  刘雪梅 《岩土力学》2008,29(2):386-391

基于实际降雨气象资料,设计了单峰降雨和8个不同时间间隔的双峰降雨计算方案,利用非饱和土力学理论,对边坡的瞬态稳定性进行了计算和分析,研究了水分在坡体内的运移对边坡稳定性的时间空间影响效应,同时考察了降雨入渗造成的土性渗透特性的改变。分析发现：一次降雨的影响历时约12 d,降雨后约0.5 d该类土质边坡最危险;不同时间间隔的两次降雨对边坡稳定的影响比单峰降雨的最小安全系数滞后约0.3 d～0.8 d,影响历时基本保持不变;土体物理力学性质、边坡最危险滑动面及其对应的安全系数随水分在坡体内渗透运移而变化。  相似文献   

Modelling and forecasting long-term dynamics of Western Baltic macrobenthic fauna in relation to climate signals and environmental change   总被引：1，自引：0，他引：1  

Joachim Grger  Heye Rumohr 《Journal of Sea Research》2006,55(4):266-277

Long-term macrobenthos data from Kiel Bight in the Western Baltic collected between 1968 and 2000 have been correlated with the winter NAO index (North Atlantic Oscillation Index) and other environmental data such as temperature, salinity and oxygen content in the bottom water in order to detect systematic patterns related to so far unexplained abiotic signals in the dynamics of zoobenthic species assemblages. The benthos data come from a cluster of five stations (Süderfahrt/ Millionenviertel) in Kiel Bay. Our investigations concentrated on the macrobenthic dynamics with a focus on the number of species m^− 2 (species richness). Using logarithms and the time series analysis approach of Box/Jenkins (ARIMA modelling, transfer function modelling) it was shown that species richness was strongly influenced by the winter NAO (adjusted for a linear time trend within the 1968-2000 period) and salinity (with a shift/lag of four years). Bootstrapping experiments (i.e. sampling from the error process) and analysis of prediction power (by means of the one- or more-years leaving-out method) showed that the parameter estimates behaved in a stable way, leading to a relatively robust model.  相似文献   

Developing a Marine Information System by Integrating Existing Ocean Models Using Object-Oriented Technology     

A. Jacob  T. Hamre  G. Evensen  K. A. Mughal 《Marine Geodesy》2003,26(1):87-106

Information systems developed for different applications within the environmental domain have common characteristics, which can potentially be abstracted for sharing and reuse of design and software modules. This article presents an approach to designing for reuse by abstracting commonalities in the design of a Marine Information System (MIS), facilitating data management in a prototype operational monitoring, forecasting, and management system for the North Atlantic and the Nordic Seas. A detailed study of the requirements and data analysis was carried out, and Object-Oriented Technology (OOT) is employed to encapsulate abstractions and to promote reuse of code and design. This article identifies the Object-Oriented Frameworks (OOFW) required to build the MIS. It also provides guidelines to environmental scientists for restructuring legacy software and employing modern programming techniques.  相似文献   

海底管道开沟机械的技术经济性能评定与选型   总被引：1，自引：0，他引：1  

张国光  顾林声 《海洋技术学报》1993,12(3):16-27

本文在对水下管道开沟机械的需求市场、实际应用和研制开发动向作深入调研的基础上，选择水下管道开沟机械特有的技术先进性、适用性、安全可靠性以及经济性评价指标，构造评价模型，对水下管道施工作业中广为应用的水力冲射开沟机械、海底管道犁、机械开沟机和土壤液化法埋管设备及其机型的技术经济性能作了较为详尽地分析对比及综合评价。在此基础上，笔者提出了水下管道开沟机械的一般选型原则和对我国海底管道开沟机械研究开发工  相似文献   

贡湖水质富营养化综合评价及初步预测   总被引：13，自引：0，他引：13  

范成新  季江 《海洋湖沼通报》1997,(3):18-24

对１９９６年７月贡湖三次调查资料进行的水质和富营养化现状综合评价显示：贡湖水质以Ⅲ－Ⅳ类为主，局部已出发Ｖ类，凯氏氮，非离子氨和总磷为主要污染物；营养型以中营养和中富营养类型分布面积较广。  相似文献